ASTM-D5453 2004
$40.63
D5453-04 Standard Test Method for Determination of Total Sulfur in Light Hydrocarbons, Motor Fuels and Oils by Ultraviolet Fluorescence
Published By | Publication Date | Number of Pages |
ASTM | 2004 | 10 |
ASTM D5453-04
Historical Standard: Standard Test Method for Determination of Total Sulfur in Light Hydrocarbons, Motor Fuels and Oils by Ultraviolet Fluorescence
ASTM D5453
Scope
1.1 This test method covers the determination of total sulfur in liquid hydrocarbons, boiling in the range from approximately 25 to 400°C, with viscosities between approximately 0.2 and 20 cSt (mm²/S) at room temperature.
1.2 Three separate interlaboratory studies (ILS) on precision, and two other investigations that resulted in an ASTM research report, have determined that this test method is applicable to naphthas, distillates, oils, ethanol, Fatty Acid Methyl Ester (FAME), and motor fuels; such as gasoline, oxygen enriched gasoline (M-85, RFG), diesel, biodiesel and jet fuel. Samples containing 1.0 to 8000 mg/kg total sulfur can be analyzed (Note 1).
Note 1—Estimates of the pooled limit of quantification (PLOQ) for each of the three precision studies were calculated. Values ranged between less than 1.0 and less than 5.0 mg/kg (see Section 8 and 14.1).
1.3 This test method is applicable for total sulfur determination in liquid hydrocarbons containing less than 0.35 % (m/m) halogen(s).
1.4 The values stated in SI units are to be regarded as standard.
1.5 This standard does not purport to address all of the safety concerns, if any, associated with its use. It is the responsibility of the user of this standard to establish appropriate safety and health practices and determine the applicability of regulatory limitations prior to use. See 3.1, 6.3, 6.4, Section 7, and 8.1.
Keywords
analysis; diesel; fluorescence; gasoline; jet fuel; kerosene; M-85; RFG; sulfur; ultraviolet
ICS Code
ICS Number Code 75.100 (Lubricants, industrial oils and related products)
DOI: 10.1520/D5453-04
PDF Catalog
PDF Pages | PDF Title |
---|---|
1 | Scope Referenced Documents Summary of Test Method Significance and Use |
2 | Apparatus Reagents FIG. 1 |
3 | FIG. 2 FIG. 3 FIG. 4 |
4 | Preparation of Apparatus Calibration and Standardization TABLE 1 TABLE 2 |
5 | Procedure Calculation |
6 | Report Quality Control Keywords TABLE 3 |
7 | X1. QUALITY CONTROL X1.1 X1.2 X1.3 X1.4 X1.5 X2. IMPORTANT FACTORS IN DIRECT INJECTION ANALYSIS OF HYDROCARBONS USING TEST METHOD D 5453 (SULFUR) X2.1 Furnace Temperature X2.2 Needle Tip Position during Injection X2.3 Injection Peak/Needle Blank X2.4 Residence Time of Needle in Furnace X2.5 Injection Size X2.6 Injection Rate and Frequency X2.7 Flow Path, Leak Check, and Back Pressure X2.8 Gas Flow Settings X2.9 Membrane Dryer Purge |
8 | X2.10 Sample Homogeneity/Calibration Response X2.11 Baseline Stability X2.12 Calibration Materials/ Standard Curve Construction X3. IMPORTANT FACTORS IN BOAT-INLET ANALYSIS OF HYDROCARBONS USING TEST METHOD D 5453 (SULFUR) X3.1 Furnace Temperature X3.2 Boat Path X3.3 Boat Entry Rate and Residence Time of Sample in Furnace X3.4 Injection Size X3.5 Injection Rate and Frequency X3.6 Boat Temperature at Time of Sample Introduction X3.7 Sample Flow Path: Leak Check and Back Pressure X3.8 Gas Flow Settings X3.9 Membrane Dryer Purge TABLE X2.1 |
9 | X3.10 Sample Homogeneity/Calibration Response X3.11 Boat Blank/Baseline Stability X3.12 Calibration Materials/ Standard Curve Construction TABLE X3.1 |