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ASTM-D5453 2004

$40.63

D5453-04 Standard Test Method for Determination of Total Sulfur in Light Hydrocarbons, Motor Fuels and Oils by Ultraviolet Fluorescence

Published By Publication Date Number of Pages
ASTM 2004 10
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ASTM D5453-04

Historical Standard: Standard Test Method for Determination of Total Sulfur in Light Hydrocarbons, Motor Fuels and Oils by Ultraviolet Fluorescence

ASTM D5453

Scope

1.1 This test method covers the determination of total sulfur in liquid hydrocarbons, boiling in the range from approximately 25 to 400°C, with viscosities between approximately 0.2 and 20 cSt (mm²/S) at room temperature.

1.2 Three separate interlaboratory studies (ILS) on precision, and two other investigations that resulted in an ASTM research report, have determined that this test method is applicable to naphthas, distillates, oils, ethanol, Fatty Acid Methyl Ester (FAME), and motor fuels; such as gasoline, oxygen enriched gasoline (M-85, RFG), diesel, biodiesel and jet fuel. Samples containing 1.0 to 8000 mg/kg total sulfur can be analyzed (Note 1).

Note 1—Estimates of the pooled limit of quantification (PLOQ) for each of the three precision studies were calculated. Values ranged between less than 1.0 and less than 5.0 mg/kg (see Section 8 and 14.1).

1.3 This test method is applicable for total sulfur determination in liquid hydrocarbons containing less than 0.35 % (m/m) halogen(s).

1.4 The values stated in SI units are to be regarded as standard.

1.5 This standard does not purport to address all of the safety concerns, if any, associated with its use. It is the responsibility of the user of this standard to establish appropriate safety and health practices and determine the applicability of regulatory limitations prior to use. See 3.1, 6.3, 6.4, Section 7, and 8.1.

Keywords

analysis; diesel; fluorescence; gasoline; jet fuel; kerosene; M-85; RFG; sulfur; ultraviolet

ICS Code

ICS Number Code 75.100 (Lubricants, industrial oils and related products)

DOI: 10.1520/D5453-04

PDF Catalog

PDF Pages PDF Title
1 Scope
Referenced Documents
Summary of Test Method
Significance and Use
2 Apparatus
Reagents
FIG. 1
3 FIG. 2
FIG. 3
FIG. 4
4 Preparation of Apparatus
Calibration and Standardization
TABLE 1
TABLE 2
5 Procedure
Calculation
6 Report
Quality Control
Keywords
TABLE 3
7 X1. QUALITY CONTROL
X1.1
X1.2
X1.3
X1.4
X1.5
X2. IMPORTANT FACTORS IN DIRECT INJECTION ANALYSIS OF HYDROCARBONS USING TEST METHOD D 5453 (SULFUR)
X2.1 Furnace Temperature
X2.2 Needle Tip Position during Injection
X2.3 Injection Peak/Needle Blank
X2.4 Residence Time of Needle in Furnace
X2.5 Injection Size
X2.6 Injection Rate and Frequency
X2.7 Flow Path, Leak Check, and Back Pressure
X2.8 Gas Flow Settings
X2.9 Membrane Dryer Purge
8 X2.10 Sample Homogeneity/Calibration Response
X2.11 Baseline Stability
X2.12 Calibration Materials/ Standard Curve Construction
X3. IMPORTANT FACTORS IN BOAT-INLET ANALYSIS OF HYDROCARBONS USING TEST METHOD D 5453 (SULFUR)
X3.1 Furnace Temperature
X3.2 Boat Path
X3.3 Boat Entry Rate and Residence Time of Sample in Furnace
X3.4 Injection Size
X3.5 Injection Rate and Frequency
X3.6 Boat Temperature at Time of Sample Introduction
X3.7 Sample Flow Path: Leak Check and Back Pressure
X3.8 Gas Flow Settings
X3.9 Membrane Dryer Purge
TABLE X2.1
9 X3.10 Sample Homogeneity/Calibration Response
X3.11 Boat Blank/Baseline Stability
X3.12 Calibration Materials/ Standard Curve Construction
TABLE X3.1
ASTM-D5453 2004
$40.63