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ASTM-E2041:2008 Edition(Redline)

ASTM-E2041:2008 Edition(Redline)

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E2041-08e1 Standard Method for Estimating Kinetic Parameters by Differential Scanning Calorimeter Using the Borchardt and Daniels Method (Redline)

Published By Publication Date Number of Pages
ASTM 2008 9
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Significance and Use

This test method is useful in research and development.

The determination of the appropriate model for a chemical reaction or transformation and the values associated with its kinetic parameters may be used in the estimation of reaction performance at temperatures or time conditions not easily tested. This use, however, is not described in this test method.

1. Scope

1.1 This test method describes the determination of the kinetic parameters of activation energy, Arrhenius pre-exponential factor, and reaction order using the Borchardt and Daniels treatment of data obtained by differential scanning calorimetry. This test method is applicable to the temperature range from 170 to 870 K ( − 100 to 600 ° C).

1.2 This treatment is applicable only to smooth exothermic reactions with no shoulders, discontinuous changes, or shifts in baseline. It is applicable only to reactions with reaction order n ≤ 2. It is not applicable to autocatalyzed reactions and, therefore, is not applicable to the determination of kinetic parameters for most thermoset curing reactions or to crystallization reactions.

1.3 The values stated in SI units are to be regarded as standard. No other units of measurement are included in this standard.

1.4 This test method is similar, but not equivalent to, ISO Method 11357, Part 5, that contains provisions for additional information not supplied by this test method.

1.5 This standard does not purport to address all of the safety concerns, if any, associated with its use. It is the responsibility of the user of this standard to establish appropriate safety and health practices and determine the applicability of regulatory limitations prior to use.

2. Referenced Documents (purchase separately) The documents listed below are referenced within the subject standard but are not provided as part of the standard.

ASTM Standards

E473 Terminology Relating to Thermal Analysis and Rheology E537 Test Method for The Thermal Stability of Chemicals by Differential Scanning Calorimetry E698 Test Method for Arrhenius Kinetic Constants for Thermally Unstable Materials Using Differential Scanning Calorimetry and the Flynn/Wall/Ozawa Method E967 Test Method for Temperature Calibration of Differential Scanning Calorimeters and Differential Thermal Analyzers E968 Practice for Heat Flow Calibration of Differential Scanning Calorimeters E1142 Terminology Relating to Thermophysical Properties E1445 Terminology Relating to Hazard Potential of Chemicals E1641 Test Method for Decomposition Kinetics by Thermogravimetry E1970 Practice for Statistical Treatment of Thermoanalytical Data

ISO Standards

ISO11357 Part 5: Determination of Temperature and/or Time of Reaction and Reaction Kinetics Available from American National Standards Institute (ANSI), 25 W. 43rd St., 4th Floor, New York, NY 10036, http://www.ansi.org.

Keywords

activation energy; Arrhenius frequency factor; Borchardt and Daniels kinetics; differential scanning calorimetry (DSC); kinetics; pre-exponential factor; reactions; Activation energy; Arrhenius kinetic constants; Borchardt and Daniels kinetics; Differential scanning calorimetry (DSC); Exothermic temperature analysis; Kinetic behavior/characteristics/parameters; Pre-exponential factor; Reactions;

ICS Code

ICS Number Code 17.200.10 (Heat. Calorimetry)

DOI: 10.1520/E2041-08E01 ASTM International is a member of CrossRef.

Citing ASTM Standards

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