{"id":364535,"date":"2024-10-20T01:51:00","date_gmt":"2024-10-20T01:51:00","guid":{"rendered":"https:\/\/pdfstandards.shop\/product\/uncategorized\/bs-iso-217662021\/"},"modified":"2024-10-26T02:56:44","modified_gmt":"2024-10-26T02:56:44","slug":"bs-iso-217662021","status":"publish","type":"product","link":"https:\/\/pdfstandards.shop\/product\/publishers\/bsi\/bs-iso-217662021\/","title":{"rendered":"BS ISO 21766:2021"},"content":{"rendered":"
This document specifies a method for the quantification of four tobacco specific nitrosamines (TSNAs) in tobacco and the following tobacco products: cigarettes, cigars and smokeless tobacco products using reversed phase high performance liquid chromatography with tandem mass spectrometry (LC-MS\/MS). The TSNAs determined with this method are: N-nitrosonornicotine (NNN), N-nitrosoanatabine (NAT), N-nitrosoanabasine (NAB) and 4-(methylnitrosamino)-1-(3-pyridyl)-1-butanone (NNK).<\/p>\n
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2<\/td>\n | National foreword <\/td>\n<\/tr>\n | ||||||
6<\/td>\n | Foreword <\/td>\n<\/tr>\n | ||||||
7<\/td>\n | Introduction <\/td>\n<\/tr>\n | ||||||
9<\/td>\n | 1 Scope 2 Normative references 3 Terms and definitions 4 Principle 5 Reagents <\/td>\n<\/tr>\n | ||||||
10<\/td>\n | 6 Apparatus <\/td>\n<\/tr>\n | ||||||
11<\/td>\n | 6.4 Autosampler vials (amber). 7 Preparation 7.1 Preparation of glassware 7.2 Preparation of solutions 7.2.1 Extraction solution, 100 mM ammonium acetate in water 7.2.2 HPLC Mobile Phase A: Water, resistivity \u2265 18,2 M\u03a9\u00b7cm at 25 \u00b0C 7.2.3 HPLC Mobile Phase B: 0,1 % acetic acid in methanol 7.3 Preparation of standards 7.3.1 General <\/td>\n<\/tr>\n | ||||||
12<\/td>\n | 7.3.2 Preparation of internal standard solutions 7.3.3 Preparation of calibration standard solutions <\/td>\n<\/tr>\n | ||||||
13<\/td>\n | 8 Sampling 8.1 General 8.2 Sample preparation 8.3 Sample extraction <\/td>\n<\/tr>\n | ||||||
14<\/td>\n | 9 Sample analysis 9.1 General 9.2 Suggested HPLC parameters 9.3 MS\/MS parameters 9.3.1 General <\/td>\n<\/tr>\n | ||||||
15<\/td>\n | 9.3.2 Quantification and qualification transitions 9.4 System suitability 9.5 Calibration 9.6 Calculation <\/td>\n<\/tr>\n | ||||||
16<\/td>\n | 10 Repeatability and reproducibility <\/td>\n<\/tr>\n | ||||||
20<\/td>\n | 11 Test report <\/td>\n<\/tr>\n | ||||||
21<\/td>\n | Annex A (informative) Sample clean-up using solid phase extraction (SPE) <\/td>\n<\/tr>\n | ||||||
23<\/td>\n | Annex B (informative) Examples of typical chromatograms <\/td>\n<\/tr>\n | ||||||
24<\/td>\n | Bibliography <\/td>\n<\/tr>\n<\/table>\n","protected":false},"excerpt":{"rendered":" Tobacco and tobacco products. Determination of tobacco-specific nitrosamines in tobacco products. Method using LC-MS\/MS<\/b><\/p>\n |