{"id":418035,"date":"2024-10-20T06:19:02","date_gmt":"2024-10-20T06:19:02","guid":{"rendered":"https:\/\/pdfstandards.shop\/product\/uncategorized\/bsi-pd-cen-tr-157452015-2\/"},"modified":"2024-10-26T11:47:02","modified_gmt":"2024-10-26T11:47:02","slug":"bsi-pd-cen-tr-157452015-2","status":"publish","type":"product","link":"https:\/\/pdfstandards.shop\/product\/publishers\/bsi\/bsi-pd-cen-tr-157452015-2\/","title":{"rendered":"BSI PD CEN\/TR 15745:2015"},"content":{"rendered":"

This Technical Report presents the study on the application of EN 14517 [2] to other oxygenates. This report supports an extension of the scope of the method, which has been explicitly requested by ISO\/TC 28 at the time of revision of EN 14517 and was agreed to result in the parallel Standard EN ISO 22854 [3].<\/p>\n

This Technical Report is published as background information to judge the approval of the use of the method for the determination of all oxygenates as mentioned in the European Fuels Directive. This Technical Report should also support the use of multidimensional chromatography as the method for disputes on oxygenates in EN 228 [1].<\/p>\n

\n

NOTE For the purposes of this document, the term \u201c% (V\/V)\u201d is used to represent the volume fraction.<\/p>\n<\/blockquote>\n

PDF Catalog<\/h4>\n\n\n\n\n\n\n\n\n\n\n\n\n\n\n\n\n\n\n\n\n\n\n\n\n\n\n\n\n\n\n\n\n\n\n\n\n\n\n\n\n\n\n\n\n\n\n\n\n\n\n\n\n
PDF Pages<\/th>\nPDF Title<\/th>\n<\/tr>\n
6<\/td>\nForeword <\/td>\n<\/tr>\n
7<\/td>\nIntroduction <\/td>\n<\/tr>\n
8<\/td>\n1 Scope
2 Normative references
3 Participating laboratories
Table 1 \u2014 Participating laboratories <\/td>\n<\/tr>\n
9<\/td>\n4 Sample set
Table 2 \u2014 Sample set of the Round Robin
Figure 1 \u2014 Overlaid section of chromatogram of samples with identified components <\/td>\n<\/tr>\n
10<\/td>\n5 Results from the round robin test
5.1 Sample 1
Table 3 \u2014 Results of sample 1 in % (V\/V) <\/td>\n<\/tr>\n
11<\/td>\nTable 4 \u2014 Results
5.2 Results sample 2
Table 5 \u2014 Results of sample 2 in % (V\/V) <\/td>\n<\/tr>\n
12<\/td>\nTable 6 \u2014 Results <\/td>\n<\/tr>\n
13<\/td>\n5.3 Results sample 3
Table 7 \u2014 Results of sample 3 in % (V\/V) <\/td>\n<\/tr>\n
14<\/td>\nTable 8 \u2014 Results <\/td>\n<\/tr>\n
15<\/td>\n5.4 Results sample 4
Table 9 \u2014 Results of sample 4 in % (V\/V) <\/td>\n<\/tr>\n
16<\/td>\nTable 10 \u2014 Results
6 Review of the data
6.1 MTBE <\/td>\n<\/tr>\n
17<\/td>\nFigure 2 \u2014 sample 1, n-Probability of MTBE – all data
Figure 3 \u2014 Sample 1, n-Probability of MTBE – laboratories 14, 18, 32 removed <\/td>\n<\/tr>\n
18<\/td>\n6.2 Methanol
Figure 4 \u2014 Sample 2, n-Probability of Methanol
6.3 t-Butanol <\/td>\n<\/tr>\n
19<\/td>\nFigure 5 \u2014 Sample 2, n-Probability t-Butanol all data
Figure 6 \u2014 Sample 2, n-Probability t-Butanol – unidentified removed
6.4 i-Propanol <\/td>\n<\/tr>\n
20<\/td>\nFigure 7 \u2014 Example of an i-propanol plot
Figure 8 \u2014 Sample 3, n-Probability i -Propanol – all data <\/td>\n<\/tr>\n
21<\/td>\nFigure 9 \u2014 Sample 3, i-Propanol – most partially identified data removed
6.5 i-Butanol
Figure 10 \u2014 Example of an i-butanol plot <\/td>\n<\/tr>\n
22<\/td>\nFigure 11 \u2014 Sample 4, n-Probability i-Butanol \u2013 all data
Figure 12 \u2014 Sample 4, n-Probability i-Butanol – unidentified removed
7 Results and conclusions <\/td>\n<\/tr>\n
23<\/td>\nTable 11 \u2014 Estimated precision data for oxygenates <\/td>\n<\/tr>\n
24<\/td>\nAnnex A (normative) Round Robin Report 2010 – 688
A.1 General
A.2 Motivation
A.2.1 General
A.2.2 Remarks <\/td>\n<\/tr>\n
25<\/td>\nA.3 Test Procedure and Protocol
A.3.1 General
A.3.2 Participating Laboratories Method A
A.3.3 Samples <\/td>\n<\/tr>\n
26<\/td>\nTable A.1 \u2014 Sample Blending in % (V\/V)
A.3.4 Results and Precision Evaluation
A.3.4.1 Results Method A \u2013 Ethanol <\/td>\n<\/tr>\n
27<\/td>\nFigure A.1 \u2014 Results Method A – Ethanol \u2013 Lab-Sample Plot <\/td>\n<\/tr>\n
28<\/td>\nTable A.2 \u2014 Results Method A – Ethanol \u2013 Laboratory Results <\/td>\n<\/tr>\n
29<\/td>\nTable A.3 \u2014 Results Method A – Ethanol \u2013 Precision Results <\/td>\n<\/tr>\n
30<\/td>\nFigure A.2 \u2014 Repeatability and Reproducibility Plot
A.3.4.2 Results Method A \u2013 Ethers <\/td>\n<\/tr>\n
31<\/td>\nFigure A.3 \u2014 Results Method A – Ethers \u2013 Lab-Sample Plot
Table A.4 \u2014 Results Method A – Ethers \u2013 Laboratory Results <\/td>\n<\/tr>\n
32<\/td>\nTable A.5 \u2014 Results Method A – Ethers \u2013 Precision Results <\/td>\n<\/tr>\n
33<\/td>\nFigure A.4 \u2014 Relative Reproducibility Plot
A.3.4.3 Results Method A \u2013 C3 to C5 Alcohols <\/td>\n<\/tr>\n
34<\/td>\nTable A.6 \u2014 Results Method A – C3 to C5 Alcohols \u2013 Laboratory Results <\/td>\n<\/tr>\n
35<\/td>\nTable A.7 \u2014 Results Method A – C3 to C5 Alcohols \u2013 Precision Results <\/td>\n<\/tr>\n
36<\/td>\nFigure A.5 \u2014 Precision Plots Method A for C3 to C5 Alcohols
A.3.4.4 Results Method A – Benzene <\/td>\n<\/tr>\n
37<\/td>\nFigure A.6 \u2014 Results Method A – Benzene \u2013 Lab-Sample Plot
Table A.8 \u2014 Results Method A – Benzene \u2013 Laboratory Results <\/td>\n<\/tr>\n
38<\/td>\nTable A.9 \u2014 Results Method A – Benzene \u2013 Precision Results <\/td>\n<\/tr>\n
39<\/td>\nFigure A.7 \u2014 Precision Plots Method A for Benzene <\/td>\n<\/tr>\n
40<\/td>\nA.4 Essential RRT Details Methods B, C, D
A.4.1 Test Procedure and Protocol
A.4.2 Participating Laboratories Method B, C and D
A.4.3 Samples
Table A.10 \u2014 Sample Blending in %(V\/V) <\/td>\n<\/tr>\n
41<\/td>\nTable A.11 \u2014 Essential RRT Details – Ethanol Methods B, C, D <\/td>\n<\/tr>\n
42<\/td>\nTable A.12 \u2014 Essential RRT Details – Ethers Methods B, C, D <\/td>\n<\/tr>\n
43<\/td>\nTable A.13 \u2014 Essential RRT Details – C3 to C5 Alcohols Methods B, C, D <\/td>\n<\/tr>\n
44<\/td>\nTable A.14 \u2014 Essential RRT Details – Benzene Method D
Table A.15 \u2014 Essential RRT Details – Methanol Methods B, C, D <\/td>\n<\/tr>\n
45<\/td>\nAnnex B (normative) Round Robin Report 2010 – 689
B.1 Methods and laboratories used
Table B.1 \u2014 Participating Laboratories (in alphabetical order) <\/td>\n<\/tr>\n
46<\/td>\nB.2 Samples
Table B.2 \u2014 Sample Blending in %(V\/V)
B.3 Results received
B.3.1 General
B.3.2 Conclusions <\/td>\n<\/tr>\n
47<\/td>\nTable B.3 \u2014 Overview of the number of participants per method
B.3.3 Overview results received
Table B.4 \u2014 Method A <\/td>\n<\/tr>\n
49<\/td>\nTable B.5 \u2014 Method B <\/td>\n<\/tr>\n
50<\/td>\nTable B.6 \u2014 Method C <\/td>\n<\/tr>\n
52<\/td>\nTable B.7 \u2014 Method D <\/td>\n<\/tr>\n
54<\/td>\nB.4 Graphs
Figure B.1 \u2014 Method A E85 RR2 <\/td>\n<\/tr>\n
55<\/td>\nFigure B.2 \u2014 Method B E85 RR2 <\/td>\n<\/tr>\n
56<\/td>\nFigure B.3 \u2014 Method C E85 RR2 <\/td>\n<\/tr>\n
57<\/td>\nFigure B.4 \u2014 Method D E85 RR2 <\/td>\n<\/tr>\n
58<\/td>\nBibliography <\/td>\n<\/tr>\n<\/table>\n","protected":false},"excerpt":{"rendered":"

Liquid petroleum products. Determination of hydrocarbon types and oxygenates via multidimensional gas chromatography method. Round Robin research report<\/b><\/p>\n\n\n\n\n
Published By<\/td>\nPublication Date<\/td>\nNumber of Pages<\/td>\n<\/tr>\n
BSI<\/b><\/a><\/td>\n2015<\/td>\n60<\/td>\n<\/tr>\n<\/tbody>\n<\/table>\n","protected":false},"featured_media":418044,"template":"","meta":{"rank_math_lock_modified_date":false,"ep_exclude_from_search":false},"product_cat":[1074,2641],"product_tag":[],"class_list":{"0":"post-418035","1":"product","2":"type-product","3":"status-publish","4":"has-post-thumbnail","6":"product_cat-75-160-20","7":"product_cat-bsi","9":"first","10":"instock","11":"sold-individually","12":"shipping-taxable","13":"purchasable","14":"product-type-simple"},"_links":{"self":[{"href":"https:\/\/pdfstandards.shop\/wp-json\/wp\/v2\/product\/418035","targetHints":{"allow":["GET"]}}],"collection":[{"href":"https:\/\/pdfstandards.shop\/wp-json\/wp\/v2\/product"}],"about":[{"href":"https:\/\/pdfstandards.shop\/wp-json\/wp\/v2\/types\/product"}],"wp:featuredmedia":[{"embeddable":true,"href":"https:\/\/pdfstandards.shop\/wp-json\/wp\/v2\/media\/418044"}],"wp:attachment":[{"href":"https:\/\/pdfstandards.shop\/wp-json\/wp\/v2\/media?parent=418035"}],"wp:term":[{"taxonomy":"product_cat","embeddable":true,"href":"https:\/\/pdfstandards.shop\/wp-json\/wp\/v2\/product_cat?post=418035"},{"taxonomy":"product_tag","embeddable":true,"href":"https:\/\/pdfstandards.shop\/wp-json\/wp\/v2\/product_tag?post=418035"}],"curies":[{"name":"wp","href":"https:\/\/api.w.org\/{rel}","templated":true}]}}