{"id":306143,"date":"2024-10-19T20:58:10","date_gmt":"2024-10-19T20:58:10","guid":{"rendered":"https:\/\/pdfstandards.shop\/product\/uncategorized\/bs-iso-172572020\/"},"modified":"2024-10-25T18:33:28","modified_gmt":"2024-10-25T18:33:28","slug":"bs-iso-172572020","status":"publish","type":"product","link":"https:\/\/pdfstandards.shop\/product\/publishers\/bsi\/bs-iso-172572020\/","title":{"rendered":"BS ISO 17257:2020"},"content":{"rendered":"
This document provides a qualitative method for the identification of rubbers by their pyrolysis products using tandem gas-chromatography\/mass spectrometry.<\/p>\n
The method applies to rubbers in the raw state and to unvulcanized and vulcanized compounds. Compounds can be based on a single rubber or a blend of two or more rubbers. Where the level of a particular rubber in a blend is <10 %, detection and identification can be difficult.<\/p>\n
A non-restrictive list of rubbers is given in Clause 4.<\/p>\n
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2<\/td>\n | undefined <\/td>\n<\/tr>\n | ||||||
7<\/td>\n | Foreword <\/td>\n<\/tr>\n | ||||||
9<\/td>\n | 1 Scope 2 Normative references 3 Terms and definitions 4 List of rubbers 4.1 Group M 4.1.1 Chloropolyethylene (CM) 4.1.2 Chlorosulfonylpolyethylene (CSM) 4.1.3 Ethylene-propylene copolymer (EPM) and Ethylene-propylene-diene terpolymer (EPDM) <\/td>\n<\/tr>\n | ||||||
10<\/td>\n | 4.1.4 Fluorocarbon rubber having substituent fluoro, perfluoroalkyl, or perfluoroalkoxy groups on the polymer chain (FKM) 4.2 Group O 4.2.1 Homopolymer of epichlorhydrin (CO), copolymer of epichlorhydrin-ethylene oxide (ECO), terpolymer of epichlorhydrin-ethylene oxide-allyl glycidyl ether (GECO) 4.3 Group Q 4.3.1 Polysiloxanes (MQ, VMQ, PVMQ) 4.4 Group R 4.4.1 Butadiene rubber (BR) 4.4.2 Chloroprene rubber (CR) 4.4.3 Isobutene-isoprene rubber (IIR), chlorinated IIR (CIIR) and brominated IIR (BIIR) 4.4.4 Natural rubber (NR) and synthetic isoprene rubber (IR) 4.4.5 Acrylonitrile-butadiene rubber (NBR), hydrogenated NBR (HNBR) and carboxylated NBR (XNBR) 4.4.6 Styrene-butadiene rubber (SBR) 4.5 Rubber blends 5 Principle <\/td>\n<\/tr>\n | ||||||
11<\/td>\n | 6 Reagents 7 Equipment <\/td>\n<\/tr>\n | ||||||
12<\/td>\n | 8 Operating conditions 8.1 General 8.2 Gas chromatograph adjustment 8.3 Extraction 8.4 Test portion 8.5 Pyrolysis 9 Interpretation of results 9.1 General <\/td>\n<\/tr>\n | ||||||
13<\/td>\n | 9.2 Group M 9.2.1 Chloropolyethylene (CM) and chlorosulfonylpolyethylene (CSM) 9.2.2 Ethylene-propylene copolymer (EPM) and Ethylene-propylene-diene terpolymer (EPDM) 9.2.3 Fluorocarbon rubber having substituent fluoro, perfluoroalkyl, or perfluoroalkoxy groups on the polymer chain (FKM) 9.3 Group O 9.3.1 Homopolymer of epichlorhydrin (CO), copolymer of epichlorhydrin-ethylene oxide (ECO), terpolymer of epichlorhydrin-ethylene oxide-allyl glycidyl ether (GECO) 9.4 Group Q 9.4.1 Polysiloxanes (MQ, VMQ, PVMQ) 9.5 Group R 9.5.1 Butadiene rubber (BR) <\/td>\n<\/tr>\n | ||||||
14<\/td>\n | 9.5.2 Chloroprene rubber (CR) 9.5.3 Isobutene-isoprene rubber (IIR), chlorinated IIR (CIIR) and brominated IIR (BIIR) 9.5.4 Natural rubber (NR) or synthetic isoprene rubber (IR) 9.5.5 Acrylonitrile-butadiene rubber (NBR), hydrogenated NBR (HNBR) and carboxylated NBR (XNBR) 9.5.6 Styrene-butadiene rubber (SBR) 10 Test report <\/td>\n<\/tr>\n | ||||||
16<\/td>\n | Annex A (informative) Schematic diagram of the chromatographic equipment <\/td>\n<\/tr>\n | ||||||
17<\/td>\n | Annex B (informative) Examples of operating conditions <\/td>\n<\/tr>\n | ||||||
18<\/td>\n | Annex C (informative) Chromatogram examples <\/td>\n<\/tr>\n | ||||||
20<\/td>\n | Annex D (informative) Chemical compounds identified in rubber pyrolysates <\/td>\n<\/tr>\n<\/table>\n","protected":false},"excerpt":{"rendered":" Rubber. Identification of polymers. Pyrolytic gas-chromatographic method using mass-spectrometric detection<\/b><\/p>\n |